Hey @fernacolo! To get more out of your GE smart toggles, switches, etc, look into Alexa routines which will allow them to respond to the time of day, if a Doorbell is rung or senses motion for instance. An Alexa device is not required for this as the Alexa app is capable of carrying out these routines.
At this time there is no feature which changes the state of the switch based off of the Alarm mode, nor can a routine be made based off of security state (Disarmed, Home, Away). Our team is constantly working on features like this, and we are always looking to improve on smart home automation. I’ve shared the ongoing interest in this feature with the team